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- W2091609903 abstract "Three co-crystals of celecoxib (CEL) and bipyridine derivatives were synthesized based on the synthon design approach and structurally characterized. The resulting two-component complexes have different unit cell parameters and noticeably different packing patterns. Surprisingly, when different organic solvents are introduced into the binary-host crystal systems, six isostructural three-component crystals are obtained. These isomorphic complexes are formed by CEL with two different sets of bipyridine co-formers containing various solvent molecules. A robust H-bonding framework between CEL dimer molecules is found to tolerate subtle changes in the structures of the co-formers and guest solvent molecules. The physicochemical properties of these isomorphic co-crystals are fully examined and compared with their corresponding non-solvate forms. The desolvation mechanism and relative thermodynamic stabilities are also discussed." @default.
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- W2091609903 date "2014-10-06" @default.
- W2091609903 modified "2023-09-28" @default.
- W2091609903 title "Isostructurality in six celecoxib co-crystals introduced by solvent inclusion" @default.
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- W2091609903 doi "https://doi.org/10.1039/c4ce01854k" @default.
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