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- W2091612910 abstract "Abstract In situ Mossbauer experiments are reported on silica-supported bimetallic FeRu and FeRh catalysts in various gaseous environments. The reduced catalysts contain iron in two states: zero-valent iron in FeRu or FeRh alloy particles, and trivalent iron in a highly dispersed iron oxide. Chemisorption of CO or NH3 at 295 K causes reduction to Fe2+ of some of the Fe3+ in the bimetallic catalysts. Preoxidation enhances the amount of Fe2+ that can be produced by subsequent CO exposure. Implications of these results on the structure of the catalyst are discussed." @default.
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- W2091612910 date "1984-07-01" @default.
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- W2091612910 title "Mössbauer investigation of bimetallic FeRu/SiO2 and FeRh/SiO2 fischer-tropsch catalysts" @default.
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- W2091612910 doi "https://doi.org/10.1016/0304-5102(84)80051-6" @default.
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