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- W2091639863 startingPage "3287" @default.
- W2091639863 abstract "Ultrasonic experiments were carried out on aqueous solutions of diamines (ethylenediamine, 1,3-propanediamine, 1,4-butanediamine, 1,5-pentanediamine, and 1,6-hexanediamine) by means of pulse technique in order to study solute-solvent interactions. Sound velocity and absorption coefficient were determined in the frequency range 15–45 MHz. The magnitude of absorption coefficient for each solution increased rapidly with concentration up to about 0.4 mol%. It is concluded that the initial rapid increase is attributed to the proton transfer in base equilibria. The absorption coefficient at the same molar concentration of each solution increases appreciably with the size of hydrocarbon chain from –(CH2)2– to –(CH2)3–. This is ascribed to the formation of icebergs around hydrocarbon groups." @default.
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- W2091639863 date "1972-11-01" @default.
- W2091639863 modified "2023-10-16" @default.
- W2091639863 title "Ultrasonic Study on Dilute Aqueous Solutions of Diamines" @default.
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- W2091639863 doi "https://doi.org/10.1246/bcsj.45.3287" @default.
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