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- W2091641519 abstract "A macrocyclic hydroperoxo chromium complex reacts with triphenyl phosphine in an acid-catalyzed oxygen-atom transfer reaction, k = 850 M-2 s-1. In a competing process, the hydroperoxo complex is converted to a dioxo chromium(V) species, which reacts with PPh3 by electron transfer, k = 4.4 x 105 M-1 s-1." @default.
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- W2091641519 date "2003-11-08" @default.
- W2091641519 modified "2023-09-23" @default.
- W2091641519 title "Direct Kinetic Studies of Atom Transfer and Electron Transfer Reactions of Hydroperoxo and High-Valent Oxo Complexes of Chromium" @default.
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- W2091641519 doi "https://doi.org/10.1021/ja0382213" @default.
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