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- W2091650227 abstract "Reaction of the complexes [(CO)3Co(μ-RC2R′)Co(CO)3] (R = R′ = CF3; R = Ph, CF3 and R′ = H) with the MoMo dinuclear derivative [Mo2Cp2(μ-SMe)2(CO)2] leads to cleavage of both CS and CH bonds with the formation of closo-octahedral Mo2CO2C2 clusters stabilised by a μ4-η2-bound alkyne. An X-ray diffraction study has shown that the two Mo2Co faces of the octahedron are capped by triply-bridging sulphur atoms." @default.
- W2091650227 created "2016-06-24" @default.
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- W2091650227 date "1991-11-01" @default.
- W2091650227 modified "2023-09-25" @default.
- W2091650227 title "Ligand shift in mixed-cluster complexes: synthesis of alkyne-bridged Co2Mo2 clusters with two triply-bridging sulphur atoms: crystal structure of [Co2Mo2(η5-Cp)2(μ3-S)2(μ4-CF3C2Me)(CO)4]" @default.
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- W2091650227 doi "https://doi.org/10.1016/0022-328x(91)80229-d" @default.
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