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• W2091666881 abstract "The synthesis of three chiral chelate nitrogen–phosphorus (S)-valine derived ligands with the potential for stereogenic nitrogen donation is described. In palladium catalysed allylic substitution reactions the ligands induced varying enantioselectivities ranging from 92% e.e. of the (R)-enantiomer to 83% e.e. of the (S)-enantiomer. Structural and spectroscopic investigations into the origin of this effect were conducted, but were inconclusive. However, the importance of the consideration of N-substituents in such systems is highlighted." @default.
• W2091666881 created "2016-06-24" @default.
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• W2091666881 date "2001-04-01" @default.
• W2091666881 modified "2023-09-27" @default.
• W2091666881 title "Investigation of the importance of nitrogen substituents in a N–P chiral ligand for enantioselective allylic alkylation" @default.
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• W2091666881 doi "https://doi.org/10.1016/s0957-4166(01)00137-9" @default.
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