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- W2091676343 abstract "Dichlorcarben reagiert mit optisch aktivem 2-Phenyl-butan (1) zu inaktivem 2-Dichlormethyl-2-phenyl-butan (2). Der Isotopie-Effekt der Reaktion beträgt kH/kD = 1.8. Methylen setzt sich mit der HCOCOCH3-Gruppe im trans-Cyclopentandiol-(1.2)-diacetat (3) unter Inversion um. Investigations of Carbenes, XIV. Stereochemistry of rhe Insertion Reaction of Carbenes with C - H-Bonds Dichlorocarbene reacts with optically active 2-phenylbutane (1) to form inactive 2-dichloromethyl-2-phenylbutane (2). The isotope effect of the reaction is kH/kD = 1.8. Methylene reacts with the HCOCOCH3 group in trans-cyclopentane-1,2-diol-diacetat (3) with inversion." @default.
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- W2091676343 date "1969-12-12" @default.
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- W2091676343 title "Untersuchungen über Carbene, XIV Stereochemischer Verlauf der Reaktion von Carbenen mit C–H-Bindungen" @default.
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- W2091676343 doi "https://doi.org/10.1002/jlac.19697290106" @default.
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