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- W2091700901 abstract "Cereal β-glucans are polysaccharides with health benefits that have been linked to their ability to increase luminal viscosity. However, the functional properties of cereal β-glucans may be diminished by the susceptibility of this polysaccharide to oxidative degradation. In this study, barley β-glucan was oxidised with hydrogen peroxide or ascorbic acid and the oxidative degradation of β-glucan was investigated using both asymmetrical flow field-flow fractionation (AsFlFFF) with aqueous solvent and high performance size exclusion chromatography (HPSEC) with LiBr in DMSO as the solvent. Oxidation was shown to cause degradation of β-glucan, the reaction being faster when oxidised with hydrogen peroxide compared with ascorbic acid. Both HPSEC and AsFlFFF showed comparable results as long as aggregates (only observed in AsFlFFF) were not included in the integration. The compact aggregates observed in oxidised samples suggest oxidation driven interactions between β-glucan molecules." @default.
- W2091700901 created "2016-06-24" @default.
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- W2091700901 date "2015-06-01" @default.
- W2091700901 modified "2023-10-11" @default.
- W2091700901 title "The oxidative degradation of barley β-glucan in the presence of ascorbic acid or hydrogen peroxide" @default.
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- W2091700901 doi "https://doi.org/10.1016/j.carbpol.2015.01.037" @default.
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