Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091701323> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2091701323 endingPage "1484" @default.
- W2091701323 startingPage "1477" @default.
- W2091701323 abstract "The new fluorine-containing diphosphine (C6H3F2-2,6)2PCH2CH2P(C6H3F2-2,6)2 I has been prepared and structurally characterized by single-crystal X-ray diffraction. The reaction between [{RhCl(µ-Cl)(η5-C5Me5)}2] and I in refluxing benzene yielded the cationic species [RhCl{η5-C5Me3[(2-CH2C6H3F-6)P(C6H3F2-2,6)CH2]2-1,3}]+, which was characterized as the BF4– salt 1. The reaction involved the regiospecific activation of two C–F bonds and two C–H bonds and the formation of two C–C bonds. In contrast, the reaction between [{IrCl(µ-Cl)(η5-C5Me5)}2] and I did not involve C–F bond activation, but resulted in the formation of the dinuclear complex [{IrCl2(η5-C5Me5)[P(C6H3F2-2,6)2CH2]}2] 2, the characterization of which was confirmed by the synthesis of the (C6F5)2PCH2CH2P(C6F5)2 analogue [{IrCl2(η5-C5Me5)[P(C6F5)2CH2]}2] 3. The complexes [MCl{(C6H3F2-2,6)2PCH2CH2P(C6H3F2-2,6)2}(η5-C5Me5)]+BF4– (M = Rh 4 or Ir 5), unlike their (C6F5)2PCH2CH2P(C6F5)2 analogues, did not undergo C–F and C–H bond activation and C–C bond formation on thermolysis. The structures of complexes 2–4 have been determined by single-crystal X-ray diffraction." @default.
- W2091701323 created "2016-06-24" @default.
- W2091701323 creator A5006830500 @default.
- W2091701323 creator A5013429330 @default.
- W2091701323 creator A5014770212 @default.
- W2091701323 creator A5031635407 @default.
- W2091701323 creator A5049018278 @default.
- W2091701323 creator A5068282875 @default.
- W2091701323 creator A5079202680 @default.
- W2091701323 creator A5085588532 @default.
- W2091701323 date "1998-01-01" @default.
- W2091701323 modified "2023-10-14" @default.
- W2091701323 title "Carbon–fluorine bond activation in the reactions between 1,2-bis[bis(2,6-difluorophenyl)phosphino]ethane and [{MCl(μ-Cl)(η5-C5Me5)}2] (M = Rh or Ir)" @default.
- W2091701323 cites W1984231780 @default.
- W2091701323 cites W1984988360 @default.
- W2091701323 cites W1997570491 @default.
- W2091701323 cites W1998665560 @default.
- W2091701323 cites W2007036412 @default.
- W2091701323 cites W2032571285 @default.
- W2091701323 cites W2056990309 @default.
- W2091701323 cites W2071153808 @default.
- W2091701323 cites W2073869085 @default.
- W2091701323 cites W2144332006 @default.
- W2091701323 cites W2326198008 @default.
- W2091701323 cites W2327344235 @default.
- W2091701323 cites W2953060498 @default.
- W2091701323 cites W3136980610 @default.
- W2091701323 doi "https://doi.org/10.1039/a800515j" @default.
- W2091701323 hasPublicationYear "1998" @default.
- W2091701323 type Work @default.
- W2091701323 sameAs 2091701323 @default.
- W2091701323 citedByCount "18" @default.
- W2091701323 countsByYear W20917013232012 @default.
- W2091701323 countsByYear W20917013232014 @default.
- W2091701323 countsByYear W20917013232016 @default.
- W2091701323 countsByYear W20917013232022 @default.
- W2091701323 crossrefType "journal-article" @default.
- W2091701323 hasAuthorship W2091701323A5006830500 @default.
- W2091701323 hasAuthorship W2091701323A5013429330 @default.
- W2091701323 hasAuthorship W2091701323A5014770212 @default.
- W2091701323 hasAuthorship W2091701323A5031635407 @default.
- W2091701323 hasAuthorship W2091701323A5049018278 @default.
- W2091701323 hasAuthorship W2091701323A5068282875 @default.
- W2091701323 hasAuthorship W2091701323A5079202680 @default.
- W2091701323 hasAuthorship W2091701323A5085588532 @default.
- W2091701323 hasConcept C115624301 @default.
- W2091701323 hasConcept C155647269 @default.
- W2091701323 hasConcept C160434732 @default.
- W2091701323 hasConcept C178790620 @default.
- W2091701323 hasConcept C183882617 @default.
- W2091701323 hasConcept C185592680 @default.
- W2091701323 hasConcept C188027245 @default.
- W2091701323 hasConcept C2777691172 @default.
- W2091701323 hasConcept C506198293 @default.
- W2091701323 hasConcept C71240020 @default.
- W2091701323 hasConcept C8010536 @default.
- W2091701323 hasConceptScore W2091701323C115624301 @default.
- W2091701323 hasConceptScore W2091701323C155647269 @default.
- W2091701323 hasConceptScore W2091701323C160434732 @default.
- W2091701323 hasConceptScore W2091701323C178790620 @default.
- W2091701323 hasConceptScore W2091701323C183882617 @default.
- W2091701323 hasConceptScore W2091701323C185592680 @default.
- W2091701323 hasConceptScore W2091701323C188027245 @default.
- W2091701323 hasConceptScore W2091701323C2777691172 @default.
- W2091701323 hasConceptScore W2091701323C506198293 @default.
- W2091701323 hasConceptScore W2091701323C71240020 @default.
- W2091701323 hasConceptScore W2091701323C8010536 @default.
- W2091701323 hasIssue "9" @default.
- W2091701323 hasLocation W20917013231 @default.
- W2091701323 hasOpenAccess W2091701323 @default.
- W2091701323 hasPrimaryLocation W20917013231 @default.
- W2091701323 hasRelatedWork W2003677112 @default.
- W2091701323 hasRelatedWork W2055437287 @default.
- W2091701323 hasRelatedWork W2058102014 @default.
- W2091701323 hasRelatedWork W2073526740 @default.
- W2091701323 hasRelatedWork W2371793935 @default.
- W2091701323 hasRelatedWork W2372164627 @default.
- W2091701323 hasRelatedWork W2385956243 @default.
- W2091701323 hasRelatedWork W2386244931 @default.
- W2091701323 hasRelatedWork W4386701586 @default.
- W2091701323 hasRelatedWork W606133901 @default.
- W2091701323 isParatext "false" @default.
- W2091701323 isRetracted "false" @default.
- W2091701323 magId "2091701323" @default.
- W2091701323 workType "article" @default.