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• W2091736109 abstract "Results of in situ high-pressure x-ray powder diffraction on the mixed-valence compound Cs${}_{2}$Au${}^{mathrm{I}}$Au${}^{mathrm{III}}$I${}_{6}$ (CsAuI${}_{3}$) are reported for pressures up to 21 GPa in a diamond-anvil cell under hydrostatic conditions. We find a reversible pressure-induced tetragonal-to-orthorhombic structural transition at 5.5--6 GPa and reversible amorphization at 12--14 GPa. Two alternative structures are proposed for the high-pressure orthorhombic phase and are discussed in the context of a possible Au valence transition." @default.
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• W2091736109 date "2013-02-06" @default.
• W2091736109 modified "2023-10-16" @default.
• W2091736109 title "Pressure-induced symmetry breaking in tetragonal CsAuI<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>3</mml:mn></mml:msub></mml:math>" @default.
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• W2091736109 doi "https://doi.org/10.1103/physrevb.87.054104" @default.
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