Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091736392> ?p ?o ?g. }
- W2091736392 abstract "Reductive amination of 2-hydroxybenzaldehyde, using a combination of NaBH 4 and ( R )-[1,1'-binaphthalene]-2,2'-diamine, served as the key step in the synthesis of the potentially tetradentate ligands ( R )- N , N' -bis(2-hydroxybenzyl)[1,1'-binaphthalene]-2,2'-diamine and ( R )- N , N' -bis(2-hydroxybenzyl)- N , N' -dimethyl[1,1'-binaphthalene]-2,2'-diamine. In analogy, amination of 2-bromobenzaldehyde with ( R )-[1,1'-binaphthalene]-2,2'-diamine produced ( R )- N , N' -bis(2-bromobenzyl)[1,1'-binaphthalene]-2,2'-diamine, whose conversion into the novel diphosphine ligand ( R )- N , N' -bis[2-(diphenylphosphino)benzyl]- N , N' -dimethyl- [1,1'-binaphthalene]-2,2'-diamine was readily attained in two steps. CD spectra of the new binaphthyl derivatives are presented." @default.
- W2091736392 created "2016-06-24" @default.
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- W2091736392 date "2000-01-01" @default.
- W2091736392 modified "2023-10-10" @default.
- W2091736392 title "Synthesis of C2-Symmetrical [1,1'-Binaphthalene]-2,2'-diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis" @default.
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- W2091736392 doi "https://doi.org/10.1135/cccc20000539" @default.
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