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• W2091750259 abstract "We removed approximately 100% of clathrated oxygen ions from the crystallographic cages in a single crystal of 12CaO.7Al2O3, leading to the formation of high-density (approximately 2 x 10(21) cm-3) electrons highly localized in the cages. The resulting electron forms a structure that we interpret as an F+ center and migrates throughout the crystal by hopping to a neighboring cage with conductivity approximately 100 siemens per centimeter, demonstrating that the encaged electron behaves as an anion. The electron anions couple antiferromagnetically with each other, forming a diamagnetic pair or singlet bipolaron. The resulting [Ca24Al28O64]4+(4e-) may be regarded as a thermally and chemically stable single crystalline electride." @default.
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• W2091750259 date "2003-08-01" @default.
• W2091750259 modified "2023-10-10" @default.
• W2091750259 title "High-Density Electron Anions in a Nanoporous Single Crystal: [Ca ₂₄ Al ₂₈ O ₆₄ ] ⁴ ⁺ (4 <i>e</i> ^- )" @default.
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• W2091750259 doi "https://doi.org/10.1126/science.1083842" @default.
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