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- W2091751574 abstract "Abstract The oxidation of bis-(p-methoxy-phenyl)telluride (PMPT) to the radical cation PMPT+ has been observed by conductivity and optical detection techniques following pulsed irradiation of methanolic PMPT-solutions. It is concluded that the oxidation of PMPT is by methoxy radicals and the rate constant k(CH3O· + PMPT) found to be 4.3 × 109 mol-1 dm3 sec-1. The yield of CH3O· obtained (GCH3O = 1.8 ± 0.2) in neutral solution is in agreement with published values from pulse radiolysis experiment with optical detection. The effect of acid on the CH3O-yield can, however, not be explained by in spur reactions as previously claimed. The yield of ethoxy radicals in ethanol radiolysis has also been determined using PMPT." @default.
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- W2091751574 date "1979-01-01" @default.
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- W2091751574 title "Methoxy radical production in methanol radiolysis" @default.
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- W2091751574 doi "https://doi.org/10.1016/0146-5724(79)90040-2" @default.
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