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- W2091757218 abstract "A theory is presented for bond-to-bond delocalization of σ-electrons and applied to the antiperiplanar effects including anomeric and gauche effects. The delocalization between geminal bonds is, surprisingly, dependent on the conformation. The geminal delocalization from the intervening bond between donor and acceptor bonds to the latter is proposed to be important as well as the vicinal delocalization from the donor to acceptor bond. Each delocalization is controlled by the orbital phase." @default.
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- W2091757218 date "1990-04-01" @default.
- W2091757218 modified "2023-09-23" @default.
- W2091757218 title "Mechanism of Delocalization of σ-Electrons from Bonds to Bonds. Conformationally Dependent Delocalization between Geminal Bonds in Antiperiplanar Effects" @default.
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- W2091757218 doi "https://doi.org/10.1246/bcsj.63.1098" @default.
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