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• W2091778936 abstract "In microfocus Raman spectroscopic measurement of micron-sized, moth-shaped single crystal of orthorhombic pohombic poly(oxymethylene) (metastable phase), the partial depolarization caused by a sharp focusing with objectives of a high magnification was investigated in order to obtain the information about the vibrational assignments. Polarized microfocus Raman spectra in the frequency range covering molecular vibrations were compared before and after the introduction of an aperture in the collimating system. The spectral difference in the (YX) polarization was observed for the bands of A–B1 and B2–B3 split-pairs, which indicated clearly that the scattering intensities of the B2 modes as well as the A modes were decreased selectively by the introduction of the aperture. In the (XX), (YY), and (XY) spectra, the B2 modes were observed as partial depolarization components of light for electric vector component along the depth direction. Utilizing these partial depolarization effects, it is possible to assign Raman-active fundamentals and to decide the unit cell orientation of the micron-sized, moth-shaped single crystal of orthorhombic poly(oxymethylene). Copyright © 2000 John Wiley & Sons, Ltd." @default.
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• W2091778936 date "2000-01-01" @default.
• W2091778936 modified "2023-09-23" @default.
• W2091778936 title "Partial depolarization effect of high-numerical-aperture objectives on polarized microfocus Raman spectra of orthorhombic poly(oxymethylene) single crystal" @default.
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• W2091778936 doi "https://doi.org/10.1002/1097-4555(200006)31:6<455::aid-jrs551>3.0.co;2-q" @default.
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