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- W2091779744 abstract "Organoaluminium(III) thioetherbis(phenolate) complexes derived from 2,2′-thiobis(4,6-diterbuthylphenolate) (Stdiol) and 2,2′-thiobis(4,6-dimethylphenolate) (Smdiol) were prepared by reaction of AlMe3 with the diol proligands LH2 (SmdiolH2, StdiolH2). Monomeric complexes of general formulae [LAlR(L′)] (L = Stdiol, R = Me, L′ = THF (1); L = Stdiol, R = Me, L′ = Et2O (2); L = Stdiol, R = iBu, L′ = THF) (3); L = Smdiol, R = Me, L′ = THF (4); L = Smdiol, R = iBu, L′ = THF (5)) and [LAlCl(THF)] (L = Stdiol (6); L = Smdiol (7)) were obtained when the reactions were performed in THF or Et2O in hexane or toluene, species of formulae [(L2Al)AlR2] (L = Stdiol, R = Me (8); L = Stdiol, R = iBu (9); L = Smdiol, R = Me (10)) were formed as evidenced by spectroscopic methods. Crystals suitable for X-ray diffraction studies were obtained for 2, 3, 4, 6, 8, 9 and 10. In these cases the sulfur atom coordinates to the aluminium center with Al–S bond lengths between 2.43–2.75 Å adopting boat–boat conformations. Compounds 1, 3, 4, and 8 were tested in the catalytic Diels–Alder cycloaddition reaction between methacrolein and cyclopentadiene showing excellent regioselectivities with good conversion yields." @default.
- W2091779744 created "2016-06-24" @default.
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- W2091779744 date "2010-01-01" @default.
- W2091779744 modified "2023-10-03" @default.
- W2091779744 title "Aluminium complexes derived from tridentate thioetherbis(phenolate) ligands and their activity in Diels–Alder catalysis" @default.
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- W2091779744 doi "https://doi.org/10.1039/b922657e" @default.
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