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- W2091781336 abstract "The extraction of water from a 1 mol dm−3 sodium perchlorate solution with trioctylphosphine oxide (TOPO) in four organic solvents and the co-extraction of water with hydrochloric, hydrobromic, hydroiodic, perchloric, nitric, and thiocyanic acids from 1 mol dm−3 of the acid solution by TOPO in hexane have been studied at 25 °C. The extraction constants of water in the absence of any of the acids, K′H2O=[TOPO·H2O]org[TOPO]org−1, were determined to be 100.40, 100.00, 10−0.12, and 10−0.36 in benzene, hexane, carbon tetrachloride, and chloroform respectively. A discrepancy from the 1: 1 molar ratio of TOPO and water in the extract was observed in the higher-TOPO-concentration region in the hexane system. The co-extraction of water with the acids disolvated by TOPO was greater in the order of HClsimeqHBr>HI>HClO4, and it was much poorer with the monosolvated acids, nitric and thiocyanic acid. The equilibria for these co-extractions of water with the acids are complicated." @default.
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- W2091781336 date "1979-06-01" @default.
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- W2091781336 title "Solvent Extraction Equilibria of Acids. VII. The Co-extraction of Water with Strong Mineral Acids by Trioctylphosphine Oxide" @default.
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- W2091781336 doi "https://doi.org/10.1246/bcsj.52.1799" @default.
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