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- W2091785222 abstract "The title quasi-one-dimensional copper oxides $(0<~x<~0.4)$ were investigated by neutron diffraction and magnetic susceptibility studies. Polyhedral ${mathrm{CuO}}_{4}$ units in the compounds were found to comprise linear chains at an interchain distance of approximately 10 AA{}. The parent-chain compound $(x=0),$ however, shows less-anisotropic magnetic behavior above 2 K, although it is of substantially antiferromagnetic $({ensuremath{mu}}_{mathrm{eff}}=1.85 {ensuremath{mu}}_{mathrm{B}}$ and ${ensuremath{Theta}}_{mathrm{W}}=ensuremath{-}46.4 mathrm{K})$ spin-chain system. A magnetic cusp gradually appears at about 100 K in T vs $ensuremath{chi}$ with the Bi substitution. The cusp $(x=0.4)$ is fairly characterized by and therefore suggests the spin-gap nature at $ensuremath{Delta}{/k}_{mathrm{B}}ensuremath{sim}80 mathrm{K}.$ The chain compounds hold electrically insulating in the composition range." @default.
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- W2091785222 date "2001-10-22" @default.
- W2091785222 modified "2023-09-25" @default.
- W2091785222 title "Crystal structure and magnetism of the linear-chain copper oxidesSr5Pb3−xBixCuO12" @default.
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- W2091785222 doi "https://doi.org/10.1103/physrevb.64.184428" @default.
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