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- W2091831214 startingPage "430" @default.
- W2091831214 abstract "The binding and migration energies for a ${mathrm{K}}^{+}$ ion on a (100) KCl surface are calculated. It is found that the most stable ${mathrm{K}}^{+}$ site is about an interionic lattice spacing above a ${mathrm{Cl}}^{ensuremath{-}}$ surface ion and the binding energy is 0.68 ev. The activation energy for lateral diffusion is 0.23 ev and the estimated vibration frequencies are ${10}^{12}$ ${mathrm{sec}}^{ensuremath{-}1}$ along the surface and 2.8ifmmodetimeselsetexttimesfi{}${10}^{12}$ ${mathrm{sec}}^{ensuremath{-}1}$ normal to the surface. From these figures it is shown that the mean path length of the ion is about 2ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}4}$ cm; the binding energy for an absorbed KCl molecule is found to be about 0.36 ev. This leads to the conclusion that the molecule will travel at most a few lattice spacings before evaporating. Some effects of this on crystal growth and additive coloring are discussed briefly." @default.
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- W2091831214 date "1955-07-15" @default.
- W2091831214 modified "2023-09-25" @default.
- W2091831214 title "Surface Adsorption and Migration Energies for KCl" @default.
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- W2091831214 doi "https://doi.org/10.1103/physrev.99.430" @default.
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