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- W2091832240 abstract "Abstract Kinetic analysis of the nonenzymic solvolysis of neryl and geranyl pyrophosphate (NPP and GPP, respectively) showed that the dissociation constants of the bis-metallic complexes with Mg 2+ and Mn 2+ were larger for NPP than for GPP by approximately one order of magnitude. Rate constants for reaction of the bis-metallic complexes were larger for NPP than for GPP. Qualitatively similar behavior was observed with complexes of Co 2+ . Extents of elimination and cyclization were increased by metal ions. Carbocyclase-catalyzed formation of cyclic monoterpene hydrocarbons in the presence of Mg 2+ involved bis-metallic complexes as the “true” substrates." @default.
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- W2091832240 date "1984-12-01" @default.
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- W2091832240 title "Complexes of bivalent cations with neryl and geranyl pyrophosphate: Their role in terpene biosynthesis" @default.
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- W2091832240 doi "https://doi.org/10.1016/0045-2068(84)90014-2" @default.
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