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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091844487> ?p ?o ?g. }

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• W2091844487 abstract "The reaction of 2-(trimethylsilyl)phenylboronic acid with alkynes in the presence of a rhodium catalyst affords benzosilole derivatives. The arylvinylrhodium intermediate undergoes formal substitution at a silicon center, resulting in the cleavage of a robust silicon-methyl bond in the trimethylsilyl group." @default.
• W2091844487 created "2016-06-24" @default.
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• W2091844487 date "2009-05-13" @default.
• W2091844487 modified "2023-10-11" @default.
• W2091844487 title "Rhodium-Catalyzed Coupling of 2-Silylphenylboronic Acids with Alkynes Leading to Benzosiloles: Catalytic Cleavage of the Carbon−Silicon Bond in Trialkylsilyl Groups" @default.
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• W2091844487 doi "https://doi.org/10.1021/ja9022978" @default.
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