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• W2091888462 startingPage "4753" @default.
• W2091888462 abstract "The first atomic layer of Kr, Xe, and Ar adsorbed on MgO smoke is explored by using adsorption isotherms. A procedure has been developed by which we produce MgO smoke powders of higher homogeneity than previously reported. On these powders, apparent two-dimensional (2D) solid-vapor, fluid-vapor, and solid-fluid coexistence regions are observed for Kr and Xe. Triple-point temperatures are estimated to be 66.6ifmmodepmelsetextpmfi{}0.5 K and 100.8ifmmodepmelsetextpmfi{}1.0 K, and the critical temperatures are estimated to be 86.8ifmmodepmelsetextpmfi{}1.0 K and 119ifmmodepmelsetextpmfi{}2.0 K, respectively, for these two elements. A comparison between Kr and Xe 2D-solid densities at the fluid-solid transition suggests that the 2D-solid phases are incommensurate with the substrate. The Ar isotherms are qualitatively different from those of Kr and Xe, showing no features corresponding to 2D phase transitions in the $Pensuremath{-}T$ range studied. A qualitative estimate places the Ar 2D critical temperature at about 65 K." @default.
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• W2091888462 date "1984-10-15" @default.
• W2091888462 modified "2023-10-16" @default.
• W2091888462 title "Adsorption of Kr, Xe, and Ar on highly uniform MgO smoke" @default.
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• W2091888462 doi "https://doi.org/10.1103/physrevb.30.4753" @default.
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