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• W2091899416 endingPage "173" @default.
• W2091899416 startingPage "168" @default.
• W2091899416 abstract "The rhenium oxides Re2O7 and ReO3 react with hydrogen peroxide solutions yielding peroxo complexes that efficiently catalyze the oxidation of olefins, aromatics, and certain organometallic compounds. In contrast, related oxides of molybdenum (MoO3) and vanadium (V2O5) do not activate H2O2 under comparable conditions. The active rhenium peroxo complex was isolated from the system Re2O7/H2O2: the crystalline red-orange, explosive compound of formula H4Re2O13 is the most oxygen rich rhenium compound isolated to date. Its structure resembles a “peroxo perrhenic acid”. The binuclear compound could be isolated in the form of a diglyme adduct, structurally defined as two corner-sharing pentagonal bipyramids with apical oxo and aquo ligands; the equatorial positions are occupied by the bridging oxygen and by n2-peroxo groups (two [O2]2− ligands per rhenium). In contrast to the known complex [CH3ReO(O2)2].H2O, the new peroxo species [O{ReO(O2)2.H2O}2] decomposes hydrolytically during the catalytic cycle and can thus not compete in terms of catalytic activity in oxidation reactions involving H2O2. Hydrolysis yields “perrhenic acid” Re2O7.2H2O, the diglyme adduct of which compound was also characterized by means of an X-ray diffraction analysis." @default.
• W2091899416 created "2016-06-24" @default.
• W2091899416 creator A5003408173 @default.
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• W2091899416 date "1996-02-01" @default.
• W2091899416 modified "2023-10-14" @default.
• W2091899416 title "The “Peroxo Perrhenic Acid” H4Re2O13: An Oxygen-Rich Metal Peroxide and Oxidation Catalyst" @default.
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• W2091899416 doi "https://doi.org/10.1002/chem.19960020208" @default.
• W2091899416 hasPublicationYear "1996" @default.
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