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- W2091904651 abstract "X-ray photo electron spectroscopy (X-ray-PES) is employed in the study of acceptor graphite intercalation compounds (GIC's) together with X-ray powder diffraction. For stage 1 to 3 graphite fluorosulfates observed shifts of the C 1s level relative to graphite are interpreted in terms of two opposing effects: a Fermi level shift to lower binding energies and a core level shift due to the partial positive charge of the graphite lattice. In addition, various levels like O 1s, F 1s or S 2p 3/2 of the molecular intercalates are studied. In addition, graphite fluorides of the composition CF x x = 0.25 − 0.80 is found to have both graphitic zones and partially oxidized layers which allow oxidative and non-oxidative intercalation by either bis(fluorosulfuryl) peroxide, S 2 O 6 F 2 , or the protonic acids HSO 3 F and HSO 3 CF 3 . The resulting intercalation compounds are studied by X-ray powder diffraction and X-ray PES." @default.
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- W2091904651 date "1991-09-01" @default.
- W2091904651 modified "2023-09-24" @default.
- W2091904651 title "X-ray - PES in graphite intercalation chemistry and the intercalation behaviour of graphite fluoride" @default.
- W2091904651 doi "https://doi.org/10.1016/s0022-1139(00)83642-8" @default.
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