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- W2091959107 abstract "The degradation of hydrocortisone phosphate in essentially neutral solutions appears to involve hydrolysis as the only significant degradative pathway. The reaction is first order with respect to the steroid ester and seems linearly dependent upon the hydrogen ion concentration. The reaction is apparently an unusual 0.44 order with respect to the catalyst. The activation energy for the overall reaction has been found to be 17.0 ± 0.5 Kcal./mole. The “frequency factor” of the Arrhenius equation has been calculated and an equation expressing the effect of both temperature and pH on the rate of the reaction is presented." @default.
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- W2091959107 date "1960-06-01" @default.
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- W2091959107 title "The Hydrolysis of Hydrocortisone Phosphate in Essentially Neutral Solutions**Received August 21, 1959, from the Merck, Sharp & Dohme Research Laboratories, West Point, Pa." @default.
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- W2091959107 doi "https://doi.org/10.1002/jps.3030490616" @default.
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