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- W2091968228 abstract "A 4:1 mixture of CH4 and BrCl diluted in He are coexpanded into a vacuum chamber and the reaction of methane with atomic chlorine is initiated by photolysis of BrCl. Near 420 nm, the resulting mixture of ground- and excited-state chlorine atoms have spatial anisotropies of βphot=−0.7 for the Cl(2P3/2)+Br channel and βphot=+1.8 for the Cl*(2P1/2)+Br channel. The speed-dependent spatial anisotropy βrxn(ν) of the CH3(ν=0) reaction product is detected by 2+1 resonance-enhanced multiphoton ionization. Our results indicate that the Cl*+CH4 reaction is unimportant in the near-threshold collision energy range of 0.13–0.16 eV, whereas the reaction with ground-state Cl atoms with CH4 excited with one quantum in the ν2 (torsion) or ν4 (bending) mode is dominant." @default.
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- W2091968228 date "2001-07-01" @default.
- W2091968228 modified "2023-09-23" @default.
- W2091968228 title "Comparison of near-threshold reactivity of ground-state and spin-orbit excited chlorine atoms with methane" @default.
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- W2091968228 doi "https://doi.org/10.1063/1.1378042" @default.
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