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- W2091968857 abstract "Abstract A new concept for a light-gated transition metal catalyst is presented based on a photo-active moiety in the outer ligand sphere of the complex which on irradiation reacts irreversibly with some part of the inner ligand sphere releasing a free coordination site. The principle is exemplified on a platinum complex for the hydrosilylation. It is proven that the catalytic properties of the complex and the properties of the photo-gate can be fine-tuned on the chemical problem independently of each other." @default.
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- W2091968857 date "2013-11-01" @default.
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- W2091968857 title "A new approach to light-gated Pt catalysts for the hydrosilylation" @default.
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- W2091968857 doi "https://doi.org/10.1016/j.jorganchem.2013.04.045" @default.
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