FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2091994501> ?p ?o ?g. }

• W2091994501 endingPage "135" @default.
• W2091994501 startingPage "127" @default.
• W2091994501 abstract "Different Fe-based materials, where iron ions are anchored on crystalline and amorphous siliceous supports are studied by FTIR spectroscopy of adsorbed NO and in the N2O decomposition reaction test. The influence of Al concentration is also considered. We show that the coordination state of Fe dramatically changes when Fe is anchored on crystalline or amorphous matrices. In crystalline Fe-ZSM-5 and Fe-silicalite samples highly coordinatively unsaturated and isolated Fe sites are present, which form Fe2+(NO)2 and Fe2+(NO)3 complexes upon NO contact. The presence of oxidic clusters, forming Fe2+(NO) complexes, whose relative concentration strictly depends upon the presence of Al and the concentration of Fe, is also evidenced. Fe-ZSM-5 sample (Si/Fe = 1120) mainly contains isolated Fe2+ ions characterised by high coordinative unsaturation. This sample also shows the highest activity in N2O decomposition, indicating that isolated and coordinatively unsaturated Fe sites are the most active precursors for the catalytic reaction. It is thought that adsorbed oxygen is formed, upon N2O decomposition, on both isolated and oxidic clusters, forming ferryl groups in the former case and bridged structures in the latter." @default.
• W2091994501 created "2016-06-24" @default.
• W2091994501 creator A5005716916 @default.
• W2091994501 creator A5025030109 @default.
• W2091994501 creator A5029701981 @default.
• W2091994501 creator A5066965562 @default.
• W2091994501 date "2005-01-01" @default.
• W2091994501 modified "2023-10-18" @default.
• W2091994501 title "Catalytic activity of Fe ions in iron-based crystalline and amorphous systems: role of dispersion, coordinative unsaturation and Al content" @default.
• W2091994501 cites W1504362703 @default.
• W2091994501 cites W1574860761 @default.
• W2091994501 cites W174241045 @default.
• W2091994501 cites W1980579226 @default.
• W2091994501 cites W1983572885 @default.
• W2091994501 cites W1983630885 @default.
• W2091994501 cites W1992662197 @default.
• W2091994501 cites W2003092651 @default.
• W2091994501 cites W2003210763 @default.
• W2091994501 cites W2004719766 @default.
• W2091994501 cites W2013340851 @default.
• W2091994501 cites W2018525398 @default.
• W2091994501 cites W2020179282 @default.
• W2091994501 cites W2024702821 @default.
• W2091994501 cites W2028462347 @default.
• W2091994501 cites W2036044786 @default.
• W2091994501 cites W2036944595 @default.
• W2091994501 cites W2045636406 @default.
• W2091994501 cites W2051964655 @default.
• W2091994501 cites W2059933145 @default.
• W2091994501 cites W2063896065 @default.
• W2091994501 cites W2065207565 @default.
• W2091994501 cites W2065745217 @default.
• W2091994501 cites W2077556786 @default.
• W2091994501 cites W2083453460 @default.
• W2091994501 cites W2083796312 @default.
• W2091994501 cites W2128543400 @default.
• W2091994501 cites W2496399649 @default.
• W2091994501 cites W26421855 @default.
• W2091994501 cites W353377913 @default.
• W2091994501 cites W84812075 @default.
• W2091994501 doi "https://doi.org/10.1016/j.jcat.2004.10.008" @default.
• W2091994501 hasPublicationYear "2005" @default.
• W2091994501 type Work @default.
• W2091994501 sameAs 2091994501 @default.
• W2091994501 citedByCount "34" @default.
• W2091994501 countsByYear W20919945012012 @default.
• W2091994501 countsByYear W20919945012014 @default.
• W2091994501 countsByYear W20919945012016 @default.
• W2091994501 countsByYear W20919945012019 @default.
• W2091994501 countsByYear W20919945012022 @default.
• W2091994501 countsByYear W20919945012023 @default.
• W2091994501 crossrefType "journal-article" @default.
• W2091994501 hasAuthorship W2091994501A5005716916 @default.
• W2091994501 hasAuthorship W2091994501A5025030109 @default.
• W2091994501 hasAuthorship W2091994501A5029701981 @default.
• W2091994501 hasAuthorship W2091994501A5066965562 @default.
• W2091994501 hasConcept C120665830 @default.
• W2091994501 hasConcept C121332964 @default.
• W2091994501 hasConcept C124681953 @default.
• W2091994501 hasConcept C127413603 @default.
• W2091994501 hasConcept C145148216 @default.
• W2091994501 hasConcept C147789679 @default.
• W2091994501 hasConcept C150394285 @default.
• W2091994501 hasConcept C161790260 @default.
• W2091994501 hasConcept C175708663 @default.
• W2091994501 hasConcept C177562468 @default.
• W2091994501 hasConcept C178790620 @default.
• W2091994501 hasConcept C179104552 @default.
• W2091994501 hasConcept C185592680 @default.
• W2091994501 hasConcept C188027245 @default.
• W2091994501 hasConcept C201268389 @default.
• W2091994501 hasConcept C42360764 @default.
• W2091994501 hasConcept C56052488 @default.
• W2091994501 hasConcept C75473681 @default.
• W2091994501 hasConcept C8010536 @default.
• W2091994501 hasConceptScore W2091994501C120665830 @default.
• W2091994501 hasConceptScore W2091994501C121332964 @default.
• W2091994501 hasConceptScore W2091994501C124681953 @default.
• W2091994501 hasConceptScore W2091994501C127413603 @default.
• W2091994501 hasConceptScore W2091994501C145148216 @default.
• W2091994501 hasConceptScore W2091994501C147789679 @default.
• W2091994501 hasConceptScore W2091994501C150394285 @default.
• W2091994501 hasConceptScore W2091994501C161790260 @default.
• W2091994501 hasConceptScore W2091994501C175708663 @default.
• W2091994501 hasConceptScore W2091994501C177562468 @default.
• W2091994501 hasConceptScore W2091994501C178790620 @default.
• W2091994501 hasConceptScore W2091994501C179104552 @default.
• W2091994501 hasConceptScore W2091994501C185592680 @default.
• W2091994501 hasConceptScore W2091994501C188027245 @default.
• W2091994501 hasConceptScore W2091994501C201268389 @default.
• W2091994501 hasConceptScore W2091994501C42360764 @default.
• W2091994501 hasConceptScore W2091994501C56052488 @default.
• W2091994501 hasConceptScore W2091994501C75473681 @default.
• W2091994501 hasConceptScore W2091994501C8010536 @default.
• W2091994501 hasIssue "1" @default.
• W2091994501 hasLocation W20919945011 @default.
• W2091994501 hasOpenAccess W2091994501 @default.
• W2091994501 hasPrimaryLocation W20919945011 @default.

• next