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• W2092016382 abstract "The physicochemical characteristics of ZnO–ZnCr2O4 (Zn–Cr–O) mixed oxides were determined by adsorption and spectroscopic methods. The catalytic activities of Zn–Cr–O was investigated for dehydrocyclization of ethylenediamine and aqueous glycerol to synthesize 2-methylpyrazine (2MP). Reductive pre-treatment was required for better 2MP yields and rate of 2MP was dependent upon strong basicity of Zn–Cr–O. Product distribution revealed that cyclocondensation of glycerol and ethylenediamine followed by homo-coupling of 2-pyrazinylmethanol occurred on moderate acid and strong base sites. On the contrary weak to moderate acidic and base sites were inefficient for homo-coupling of 2-pyrazinylmethanol. Role of acid-base properties was examined by pyridine and 2,6-dimethylpyridine poisoning studies." @default.
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• W2092016382 date "2014-01-01" @default.
• W2092016382 modified "2023-09-26" @default.
• W2092016382 title "Influence of acid-base sites on ZnO–ZnCr2O4 catalyst during dehydrocyclization of aqueous glycerol and ethylenediamine for the synthesis of 2-methylpyrazine: Kinetic and mechanism studies" @default.
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• W2092016382 doi "https://doi.org/10.1016/j.apcata.2013.10.023" @default.
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