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• W2092022785 startingPage "1530" @default.
• W2092022785 abstract "CH3CoIIIPc (Pc = dianion of phthalocyanine) has been characterized by equilibrium studies of its trans axial ligation and cyclic voltammetry as a relatively “electron poor” model of methylcobalamin, which in noncoordinating solvents persists as a five-coordinate complex. Axial base (N-donors, PBu3, SCN-, weakly binding O-donors) inhibition of methyl transfer from CH3CoIIIPc shows that the reaction proceeds via the reactive five-coordinate species, even in coordinating solvents. The virtual inactivity of six-coordinate CH3CoIIIPc(L) complexes provides a reference point for important biological processes." @default.
• W2092022785 created "2016-06-24" @default.
• W2092022785 creator A5030168089 @default.
• W2092022785 date "2005-01-22" @default.
• W2092022785 modified "2023-09-24" @default.
• W2092022785 title "Methyl Transfer Reactivity of Five-Coordinate CH₃Co^IIIPc" @default.
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• W2092022785 doi "https://doi.org/10.1021/ic048698v" @default.
• W2092022785 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15732996" @default.
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