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- W2092023615 abstract "Summary The photolysis of tris(trimethylsilyl)phenylsilane (I) in the presence of allyl chloride, allyl bromide, 2-cyclohexenyl chloride, 2-cyclohexenyl bromide and 2-methylallyl chloride resulted in formation of the respective 1-(2-alkenyl)-1-halo-1-phenyltrimethyldisilanes in moderate yields. Irradiation of I in the presence of crotyl chloride, 1-methylallyl chloride, prenyl chloride and 1,1-dimethylallyl chloride afforded the corresponding α- and γ-substituted chlorodisilanes. Photolysis of I in the presence of allyl ethyl ether produced 1-phenyl-1-trimethylsilyl-2-ethoxymethyl-1-silacyclopropane, although this product was not isolated. The reaction of this silacyclopropane with hydrogen chloride, methanol and boron trifluoride etherate is described." @default.
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- W2092023615 date "1981-07-01" @default.
- W2092023615 modified "2023-10-14" @default.
- W2092023615 title "Photolysis of organopolysilanes. Reactions of trimethylsilylphenylsilylene with allylic halides and allyl ethyl ether" @default.
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- W2092023615 doi "https://doi.org/10.1016/s0022-328x(81)80002-2" @default.
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