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- W2092023886 abstract "The solution structure and equilibria of vanadium(V), molybdenum(VI), and tungsten(VI) complexes formed by ethylenediaminetetra-acetic (H4edta), ethylenediamine-NN′-diacetic (H2edda), nitrilotriacetic (H3nta), and iminodiacetic (H2ida) acids have been investigated potentiometrically and spectrophotometrically. If Yn– represents the fully dissociated ligand anion, all the 1 : 1 complexes have the formula [VO2Y](n–1)–, [MoO3Y]n–, and [WO3Y]n–. A 1 : 2 vanadium(V)-ida, a 2 : 1 molybdenum(VI)- or tungsten(VI)–edta and two protonated 1 : 1 vanadium(V)–edta chelate complexes are also formed. The formation constants of the 1 : 1 complexes increase with the number of chelate rings for the same metal and decrease from VV to MoVI and WVI for a given ligand. The oxometal ions have a greater affinity for the nitrogen of the amine function than for the acetate oxygen." @default.
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- W2092023886 date "1979-01-01" @default.
- W2092023886 modified "2023-09-25" @default.
- W2092023886 title "Determination and comparison of stability constants of vanadium(V), molybdenum(VI), and tungsten(VI) aminocarboxylate complexes" @default.
- W2092023886 doi "https://doi.org/10.1039/dt9790001372" @default.
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