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• W2092038034 abstract "Laser flash photolysis of Cl2/O2 mixtures has been employed in conjunction with Cl(2P32) detection by time-resolved resonance fluorescence spectroscopy to investigate equilibration kinetics for the reactions Cl + O2 + O2 ⇌ ClOO + O2 at temperatures of 181–200 K and O2 pressures of 15–40 Torr. The third-order rate coefficient for the association reaction at 186.5 ± 5.5 K is (8.9 ± 2.9) × 10−33 cm6 molecule−2 s−1 and the equilibrium constant (Kp) at 185.4 K is 18.9 atm−1 (factor of 1.7 uncertainty). A third law analysis of our data leads to a value for the ClOO bond dissociation energy of 4.76 ± 0.49 kcal mol−1." @default.
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• W2092038034 date "1991-04-01" @default.
• W2092038034 modified "2023-09-27" @default.
• W2092038034 title "Thermochemistry and kinetics of the Cl + O2 association reaction" @default.
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• W2092038034 doi "https://doi.org/10.1016/0009-2614(91)85168-v" @default.
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