FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092051644> ?p ?o ?g. }

• W2092051644 endingPage "5774" @default.
• W2092051644 startingPage "5774" @default.
• W2092051644 abstract "A series of new rigid distibines, 1,8-bis(R(2)Sb)naphthalene (R = Me: (); R = Ph: ()), and chiral distibines, 2,2'-bis(R(2)Sb)-1,1'-binaphthyl (R = Me: (); R = Ph: () obtained as racemic mixtures) and the discrete enantiomers of 4,5-bis((R(2)Sb)methyl)-2,2-dimethyl-1,3-D/L-dioxolane (R = Me: () (l), () (d); R = Ph: () (l), () (d)) have been obtained in high yields, using either electrophilic halostibine reagents with di-lithium reagents (()-()) or nucleophilic stibide reagents with dibromo-derivatives (()-()). The distorted octahedral complexes [Mo(CO)(4)(L)], L = ()-(), planar [PtCl(2)(L)], L = (), (), (), (), and neutral, five-coordinate [RhCl(cod)(L)], L = (), (), (), are reported and trends in the spectroscopic data are discussed in terms of the ligand donor properties. Crystal structures of () and [Mo(CO)(4)()] reveal significant structural changes occur upon coordination, and these are also reflected in the solution NMR spectroscopic parameters. Changes in the C-Sb-C angles and C-Sb bond distances upon coordination of () are discussed in term of increased s/p orbital mixing. Air oxidation of () forms a very unusual stibine oxide, the structure of which shows a distorted Sb(4)O(4) cubane core (bridging O atoms) with two orthogonal naphthalene units." @default.
• W2092051644 created "2016-06-24" @default.
• W2092051644 creator A5018515797 @default.
• W2092051644 creator A5021243367 @default.
• W2092051644 creator A5042515459 @default.
• W2092051644 creator A5045654390 @default.
• W2092051644 date "2008-01-01" @default.
• W2092051644 modified "2023-10-04" @default.
• W2092051644 title "Preparation and properties of sterically demanding and chiral distibine ligands" @default.
• W2092051644 cites W1964700751 @default.
• W2092051644 cites W1966080154 @default.
• W2092051644 cites W1966380113 @default.
• W2092051644 cites W1967645380 @default.
• W2092051644 cites W1998821231 @default.
• W2092051644 cites W2002121219 @default.
• W2092051644 cites W2005970380 @default.
• W2092051644 cites W2013679888 @default.
• W2092051644 cites W2016256534 @default.
• W2092051644 cites W2040539348 @default.
• W2092051644 cites W2041354335 @default.
• W2092051644 cites W2042306297 @default.
• W2092051644 cites W2054312524 @default.
• W2092051644 cites W2060070478 @default.
• W2092051644 cites W2061257257 @default.
• W2092051644 cites W2066062835 @default.
• W2092051644 cites W2068358077 @default.
• W2092051644 cites W2070698983 @default.
• W2092051644 cites W2070934456 @default.
• W2092051644 cites W2090671801 @default.
• W2092051644 cites W2093020828 @default.
• W2092051644 cites W2112757205 @default.
• W2092051644 cites W2135865437 @default.
• W2092051644 cites W2146739886 @default.
• W2092051644 cites W2316640390 @default.
• W2092051644 cites W2950106118 @default.
• W2092051644 cites W2952983696 @default.
• W2092051644 cites W3138093308 @default.
• W2092051644 cites W2083599904 @default.
• W2092051644 doi "https://doi.org/10.1039/b808493a" @default.
• W2092051644 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18941665" @default.
• W2092051644 hasPublicationYear "2008" @default.
• W2092051644 type Work @default.
• W2092051644 sameAs 2092051644 @default.
• W2092051644 citedByCount "14" @default.
• W2092051644 countsByYear W20920516442013 @default.
• W2092051644 countsByYear W20920516442017 @default.
• W2092051644 countsByYear W20920516442018 @default.
• W2092051644 countsByYear W20920516442019 @default.
• W2092051644 countsByYear W20920516442021 @default.
• W2092051644 countsByYear W20920516442022 @default.
• W2092051644 crossrefType "journal-article" @default.
• W2092051644 hasAuthorship W2092051644A5018515797 @default.
• W2092051644 hasAuthorship W2092051644A5021243367 @default.
• W2092051644 hasAuthorship W2092051644A5042515459 @default.
• W2092051644 hasAuthorship W2092051644A5045654390 @default.
• W2092051644 hasConcept C115624301 @default.
• W2092051644 hasConcept C116569031 @default.
• W2092051644 hasConcept C147789679 @default.
• W2092051644 hasConcept C161790260 @default.
• W2092051644 hasConcept C170493617 @default.
• W2092051644 hasConcept C178790620 @default.
• W2092051644 hasConcept C185592680 @default.
• W2092051644 hasConcept C198819137 @default.
• W2092051644 hasConcept C201194858 @default.
• W2092051644 hasConcept C2776776902 @default.
• W2092051644 hasConcept C2777039156 @default.
• W2092051644 hasConcept C2777716191 @default.
• W2092051644 hasConcept C40875361 @default.
• W2092051644 hasConcept C486523 @default.
• W2092051644 hasConcept C50027330 @default.
• W2092051644 hasConcept C55493867 @default.
• W2092051644 hasConcept C71240020 @default.
• W2092051644 hasConcept C8010536 @default.
• W2092051644 hasConceptScore W2092051644C115624301 @default.
• W2092051644 hasConceptScore W2092051644C116569031 @default.
• W2092051644 hasConceptScore W2092051644C147789679 @default.
• W2092051644 hasConceptScore W2092051644C161790260 @default.
• W2092051644 hasConceptScore W2092051644C170493617 @default.
• W2092051644 hasConceptScore W2092051644C178790620 @default.
• W2092051644 hasConceptScore W2092051644C185592680 @default.
• W2092051644 hasConceptScore W2092051644C198819137 @default.
• W2092051644 hasConceptScore W2092051644C201194858 @default.
• W2092051644 hasConceptScore W2092051644C2776776902 @default.
• W2092051644 hasConceptScore W2092051644C2777039156 @default.
• W2092051644 hasConceptScore W2092051644C2777716191 @default.
• W2092051644 hasConceptScore W2092051644C40875361 @default.
• W2092051644 hasConceptScore W2092051644C486523 @default.
• W2092051644 hasConceptScore W2092051644C50027330 @default.
• W2092051644 hasConceptScore W2092051644C55493867 @default.
• W2092051644 hasConceptScore W2092051644C71240020 @default.
• W2092051644 hasConceptScore W2092051644C8010536 @default.
• W2092051644 hasIssue "42" @default.
• W2092051644 hasLocation W20920516441 @default.
• W2092051644 hasLocation W20920516442 @default.
• W2092051644 hasOpenAccess W2092051644 @default.
• W2092051644 hasPrimaryLocation W20920516441 @default.
• W2092051644 hasRelatedWork W167857991 @default.
• W2092051644 hasRelatedWork W1969215021 @default.

• next