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• W2092065183 abstract "The optical spectrum of the dithiocarbamate radical (dtc) R2NCS2 (RCH3, C2H5, n- Bu; Bubutyl) and its kinetic parameters have been detected by means of laser flash photolysis of thiuram disulphide (tds) [R2NC(S)S]2 and dithiocarbamate anion (dtc−) in different solvents. The dtc absorption band has a maximum at about 600 nm, the extinction coefficient of the band being about 3100 1 mol−1 cm−1. In all the solvents studied, the radicals decay owing to recombination at almost the diffusion rate. Quantum-chemical calculation of the geometry and spectra of dtc radicals has been performed in a many- configuration approximation. A good fit of the calculation results to experimental spectral data has been obtained." @default.
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• W2092065183 date "1992-09-01" @default.
• W2092065183 modified "2023-09-30" @default.
• W2092065183 title "Dithiocarbamate radicals in laser flash photolysis of thiuram disulphide and dithiocarbamate anion: calculation of optical spectra" @default.
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• W2092065183 doi "https://doi.org/10.1016/1010-6030(92)85239-q" @default.
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