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- W2092118047 abstract "This work focuses upon the effects of electrolyte composition, specifically the role of Li+ and I− ions, on the resultant photovoltaic performance of dye-sensitized solar cells (DSCs) based on a new Os(II) polypyridine complex of mixed denticity, [Os(tBu3tpy)(dcbpyH2)(NCS)]PF6 (1). Photophysical and electrochemical characterization of 1 confirmed the suitability of this dye to serve as a sensitizer for regenerative DSCs on mesoscopic titania films. Device photovoltaic performances were assessed by measuring external quantum efficiencies as a function of wavelength, and current−voltage curves, the latter under simulated AM1.5G one-sun illumination. Varying the concentration of LiI in the redox electrolyte affects the short-circuit photocurrent (JSC), open-circuit voltage (VOC), fill factor (ff), power conversion efficiency (η), and external quantum efficiency (EQE) of the individual devices. Increasing the concentration of LiI results in enormous increases in JSC in the Os(II)-based devices accompanied by ..." @default.
- W2092118047 created "2016-06-24" @default.
- W2092118047 creator A5017888744 @default.
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- W2092118047 date "2010-03-04" @default.
- W2092118047 modified "2023-09-27" @default.
- W2092118047 title "Electrolyte-Dependent Photovoltaic Responses in Dye-Sensitized Solar Cells Based on an Osmium(II) Dye of Mixed Denticity" @default.
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- W2092118047 doi "https://doi.org/10.1021/jp100279e" @default.
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