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• W2092118090 abstract "Hydrogen cyanide (HCN) for use in ion preparation can be generated in the gas phase by the neutral-neutral reaction of trimethylsilyl cyanide (Me3SiCN) and water in a flowing afterglow mass spectrometer. We demonstrate that the approach can be used to generate a wide range of HCN solvated ions such as F−(HCN), Cl−(HCN), CN−(HCN), PhNO2·−(HCN), Me3SiO−(HCN),and PhSiF4−(HCN), many of which are otherwise difficult to generate. The bond dissociation energy of CN−(HCN), generated by using this approach, has been measured by using energy-resolved collision-induced issociation (CID) to be 0.87 ± 0.07 eV." @default.
• W2092118090 created "2016-06-24" @default.
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• W2092118090 date "2006-01-01" @default.
• W2092118090 modified "2023-09-26" @default.
• W2092118090 title "In situ generation of HCN for mass spectrometric studies" @default.
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• W2092118090 doi "https://doi.org/10.1016/j.jasms.2005.08.018" @default.
• W2092118090 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16352440" @default.
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