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- W2092120882 abstract "Single crystals of synthetic (PbCO(3))(2).BaF(2), bis[lead(II) carbonate] barium difluoride, have been grown under hydrothermal conditions. The compound crystallizes in the ordered hydrocerussite [(PbCO(3))(2).Pb(OH)(2)] structure and can be derived from a close packing of the metal atoms with a stacking sequence of [c(h)(2)](3) along the c axis. O and F atoms are situated approximately in the tetrahedral voids, resulting in the formation of a slightly distorted [BaF(6)O(6)] icosahedron and a [1+6+3]-coordinate Pb atom, with one short bond to F, six bonds to O and three longer bonds to additional O atoms. The carbonate group deviates only slightly from the geometry of an equilateral triangle." @default.
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- W2092120882 date "2002-08-31" @default.
- W2092120882 modified "2023-10-03" @default.
- W2092120882 title "The ordered hydrocerussite-type structure of (PbCO<sub>3</sub>)<sub>2</sub>·BaF<sub>2</sub>" @default.
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- W2092120882 doi "https://doi.org/10.1107/s0108270102013884" @default.
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