Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092124502> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2092124502 endingPage "49" @default.
- W2092124502 startingPage "43" @default.
- W2092124502 abstract "Nine ironporphyrins and eight manganeseporphyrins were synthesized, and their selective catalysis for the oxidation of the secondary and tertiary carbon–hydrogen bonds of 2-methyl-butane with PhIO was studied. The proportion of the oxidation product of tertiary carbon–hydrogen bond to the one of secondary carbon–hydrogen bond was 3:1 when ironporphyrins were used as catalysts, and 2.3:1 when manganeseporphyrins were used as catalysts. The research showed that the substituting groups on the porphyrin rings influenced the catalytic selectivity of metalloporphyrins for the oxidation of the secondary and tertiary carbon–hydrogen bonds as well as the reaction yields. The electron-attracting groups on benzene rings of ironporphyrins increased the catalytic selectivity of ironporphyrins for the tertiary carbon–hydrogen bond oxidation and the reaction speeds, and the electron-releasing groups increased the catalytic selectivity for secondary carbon–hydrogen bond oxidation and reduced the reaction speeds. Both electron-attracting and -releasing groups on benzene rings of manganeseporphyrins enhanced the catalytic selectivity of manganeseporphyrins for the secondary carbon–hydrogen bond oxidation." @default.
- W2092124502 created "2016-06-24" @default.
- W2092124502 creator A5017709527 @default.
- W2092124502 creator A5031647041 @default.
- W2092124502 creator A5039367389 @default.
- W2092124502 creator A5054700738 @default.
- W2092124502 date "2001-05-01" @default.
- W2092124502 modified "2023-09-26" @default.
- W2092124502 title "Study of the selective catalysis of metalloporphyrins for 2-methyl-butane oxidation with PhIO under mild conditions" @default.
- W2092124502 cites W100346553 @default.
- W2092124502 cites W1963547603 @default.
- W2092124502 cites W1969026406 @default.
- W2092124502 cites W1969835063 @default.
- W2092124502 cites W1975380009 @default.
- W2092124502 cites W1996269523 @default.
- W2092124502 cites W1998959489 @default.
- W2092124502 cites W2003946693 @default.
- W2092124502 cites W2023398515 @default.
- W2092124502 cites W2024957486 @default.
- W2092124502 cites W2032057821 @default.
- W2092124502 cites W2049865119 @default.
- W2092124502 cites W2051849766 @default.
- W2092124502 cites W2063249326 @default.
- W2092124502 cites W2073356400 @default.
- W2092124502 cites W2075491748 @default.
- W2092124502 cites W2086433318 @default.
- W2092124502 cites W2101183114 @default.
- W2092124502 cites W2333065922 @default.
- W2092124502 cites W2496776099 @default.
- W2092124502 cites W2950895438 @default.
- W2092124502 doi "https://doi.org/10.1016/s1381-1169(01)00066-8" @default.
- W2092124502 hasPublicationYear "2001" @default.
- W2092124502 type Work @default.
- W2092124502 sameAs 2092124502 @default.
- W2092124502 citedByCount "8" @default.
- W2092124502 countsByYear W20921245022012 @default.
- W2092124502 countsByYear W20921245022016 @default.
- W2092124502 crossrefType "journal-article" @default.
- W2092124502 hasAuthorship W2092124502A5017709527 @default.
- W2092124502 hasAuthorship W2092124502A5031647041 @default.
- W2092124502 hasAuthorship W2092124502A5039367389 @default.
- W2092124502 hasAuthorship W2092124502A5054700738 @default.
- W2092124502 hasConcept C104779481 @default.
- W2092124502 hasConcept C118792377 @default.
- W2092124502 hasConcept C140205800 @default.
- W2092124502 hasConcept C155647269 @default.
- W2092124502 hasConcept C159985019 @default.
- W2092124502 hasConcept C161790260 @default.
- W2092124502 hasConcept C178790620 @default.
- W2092124502 hasConcept C185592680 @default.
- W2092124502 hasConcept C192562407 @default.
- W2092124502 hasConcept C2777691172 @default.
- W2092124502 hasConcept C2778717364 @default.
- W2092124502 hasConcept C512968161 @default.
- W2092124502 hasConcept C75473681 @default.
- W2092124502 hasConceptScore W2092124502C104779481 @default.
- W2092124502 hasConceptScore W2092124502C118792377 @default.
- W2092124502 hasConceptScore W2092124502C140205800 @default.
- W2092124502 hasConceptScore W2092124502C155647269 @default.
- W2092124502 hasConceptScore W2092124502C159985019 @default.
- W2092124502 hasConceptScore W2092124502C161790260 @default.
- W2092124502 hasConceptScore W2092124502C178790620 @default.
- W2092124502 hasConceptScore W2092124502C185592680 @default.
- W2092124502 hasConceptScore W2092124502C192562407 @default.
- W2092124502 hasConceptScore W2092124502C2777691172 @default.
- W2092124502 hasConceptScore W2092124502C2778717364 @default.
- W2092124502 hasConceptScore W2092124502C512968161 @default.
- W2092124502 hasConceptScore W2092124502C75473681 @default.
- W2092124502 hasIssue "1-2" @default.
- W2092124502 hasLocation W20921245021 @default.
- W2092124502 hasOpenAccess W2092124502 @default.
- W2092124502 hasPrimaryLocation W20921245021 @default.
- W2092124502 hasRelatedWork W2021875819 @default.
- W2092124502 hasRelatedWork W2034035521 @default.
- W2092124502 hasRelatedWork W2044610687 @default.
- W2092124502 hasRelatedWork W2081446226 @default.
- W2092124502 hasRelatedWork W2084922256 @default.
- W2092124502 hasRelatedWork W2349522820 @default.
- W2092124502 hasRelatedWork W2360157367 @default.
- W2092124502 hasRelatedWork W2367457648 @default.
- W2092124502 hasRelatedWork W2384573759 @default.
- W2092124502 hasRelatedWork W3213410839 @default.
- W2092124502 hasVolume "170" @default.
- W2092124502 isParatext "false" @default.
- W2092124502 isRetracted "false" @default.
- W2092124502 magId "2092124502" @default.
- W2092124502 workType "article" @default.