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- W2092125511 abstract "Abstract Five novel thiocyanate complexes [Mn(bpzm)2(NCS)2] (1), [Mn(bdmpzm)2(NCS)2] (2), [Co(bpzm)2(NCS)2] (3), [Co(bdmpzm)2(NCS)2] (4) and [Co(bdmpzm)(NCS)2] (5) (bpzm = bis(pyrazol-1-yl)methane and bdmpzm = bis(3,5-dimethylpyrazol-1-yl)methane) were synthesized and characterized structurally (by single X-ray analysis) and spectroscopically. The studies showed influence of central metal ion and organic co-ligands on the geometry of the thiocyanate Co(II) and Mn(II) complexes. Variable-temperature magnetic susceptibility measurements revealed occurrence of ferromagnetic interactions in 1 and the antiferromagnetic ones for the remaining complexes. The fluorescence properties of the Co(II) complexes were examined in solution and compared with the free ligands." @default.
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- W2092125511 date "2013-06-01" @default.
- W2092125511 modified "2023-10-17" @default.
- W2092125511 title "Thiocyanate manganese(II) and cobalt(II) complexes of bis(pyrazol-1-yl)methane and bis(3,5-dimethylpyrazol-1-yl)methane – Syntheses, spectroscopic characterization, X-ray structure and magnetic properties" @default.
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- W2092125511 doi "https://doi.org/10.1016/j.poly.2013.03.052" @default.
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