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• W2092129025 abstract "Aus den Daten einer vollständigen Analyse der 1H-NMR-Spektren der C6-Cycloolefine ergeben sich nach der Karplus-Relation und der R-Wert-Methode Torsionswinkel, die für Cyclohexen (2) eine Halbsessel-Konformation, für 1,3-Cyclohexadien (3) eine nicht planare und für 1,4-Cyclohexadien (4) eine planare oder nahezu planare Konformation anzeigen. Die Diskussion dieser Ergebnisse erfolgt auf der Basis von Deformationen der CCC-Bindungs- und -Torsionswinkel, die durch Spannungskräfte hervorgerufen werden. 1H-Nuclear Magnetic Resonance Investigations of C6-Cycloolefins The 1H NMR spectra of the C6-cycloolefins were completely analysed. In connection with the Karplus-relation and the R-value method the resulting data yielded torsional angles which show a half-chair conformation for cyclohexene (2), for 1,3-cyclohexadiene (3) a not quite planar, and for 1,4-cyclohexadiene (4) a planar or nearly planar conformation. These results were discussed in terms of deformations of CCC-bond angles and torsional angles caused by strain forces." @default.
• W2092129025 created "2016-06-24" @default.
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• W2092129025 date "1978-06-01" @default.
• W2092129025 modified "2023-10-16" @default.
• W2092129025 title "¹ H‐Kernresonanz‐spektroskopische Untersuchungen an C ₆ ‐Cycloolefinen" @default.
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• W2092129025 doi "https://doi.org/10.1002/cber.19781110633" @default.
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