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- W2092133591 abstract "Resume Na 2 U 2 O 7 , isotype de CaUO 4 , est rhomboedrique R 3 m avec a = 3,911(2) A , c = 17,857(5) A , Z = 3 2 . La structure a ete affinee jusqu'a R = 0,082, R w = 0,096 pour 262 reflexions independantes avec I ⩾ 3 σ ( I ). Cette etude montre que les atomes uranium et O 2 sont delocalises et que les lacunes d'oxygene sont situees sur les sites O 1 de la liaison uranyle. En consequence, la formule de l'unite asymetrique est Na(UO 1,5 )O 2 et non pas Na(UO 2 )O 1,5 comme le suggerait son analogie structurale avec Ca(UO 2 )O 2 ." @default.
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- W2092133591 date "1986-05-01" @default.
- W2092133591 modified "2023-09-25" @default.
- W2092133591 title "Na2U2O7: Synthèse et structure d'un monocristal" @default.
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- W2092133591 doi "https://doi.org/10.1016/0022-5088(86)90198-0" @default.
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