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- W2092137456 abstract "Studies are reported on the influence of preparative variables on the dispersion and alloying of the metals in silica-supported PtAu, RhCu, and (in part) PtSn. Tests of n-hexane conversion on selected catalyst samples using a pulse reactor are presented. It is shown that (i) while there is no evidence from X-ray diffraction of significant alloying in PtAu samples from various preparations, catalytic results show some interaction between the two metallic elements and (ii) samples of 15% Rn: 85% Cu remain poorly alloyed, a rhodium-rich region remaining even with reasonably severe heat treatment prior to and during reaction: Even then, such a catalyst shows a selectivity of ~25% for C5 + C6 cyclic products whereas 100% Cu has only a small, and 100% Rh a negligible, cyclization selectivity." @default.
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- W2092137456 date "1978-09-01" @default.
- W2092137456 modified "2023-10-12" @default.
- W2092137456 title "Preparation of supported platinum-gold, platinum-tin, and rhodium-copper catalysts and some tests with n-hexane/hydrogen reactant" @default.
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- W2092137456 doi "https://doi.org/10.1016/0021-9517(78)90046-5" @default.
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