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- W2092145366 abstract "The Rh and Ni catalyzed hydrosilylation of butadiynes to chiral allenes in the presence of chiral phosphine ligands is described. For the first time an enantiomeric excess up to 27% was achieved using [Rh(COD)Cl]2/(−)-PPM and up to 11% using NiCl2[(−)-DIOP]." @default.
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- W2092145366 date "2000-05-01" @default.
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- W2092145366 title "A new asymmetric synthesis of optically active allenes via metal catalyzed hydrosilylation" @default.
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- W2092145366 doi "https://doi.org/10.1016/s0022-328x(00)00206-0" @default.
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