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- W2092151012 abstract "Abstract We have investigated the effect of pressure on the Raman spectra of the ternary chalcogenides CulnSe2 (chalcopyrite structure) and LiInSe2 (β-NaFeO2 structure) for pressures extending well above their first pressure-induced phase transitions. Sign and magnitude of Griineisen parameters are discussed by comparing to related tetrahedrally coordinated chalcogenides. Discontinuous changes of the Raman frequencies indicate pressure-induced phase transitions at 8.0±0.3 and 4.2±0.2 GPa in CuInSe2 and in LiInSe2, respectively. The Raman spectra of the low-pressure phases are not recovered after pressure release but a highly disordered structure is induced. In the case of LiInSe2, the effect of laser heating on the Raman spectra of the high-pressure phase is investigated and discussed in light of recent high-pressure x-ray investigations." @default.
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- W2092151012 date "1992-05-01" @default.
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- W2092151012 title "Raman scattering and phase changes of CulnSe2and LiInSe2at high pressure" @default.
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- W2092151012 doi "https://doi.org/10.1080/08957959208245609" @default.
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