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- W2092161877 abstract "The magnitude of 1J(15N13C) in para-substituted benzenediazonium ions has been used to assess the importance of the several resonance forms contributing to the ground state of the ion. From a comparison of values observed in 4-nitro- and 4-dimethylamino-benzenediazonium ions and their respective 3,5-dimethyl derivatives, it is concluded that diazo-type structures are important only with strong electron-releasing substituents in the aromatic ring. INDO–SOS–MO calculations indicate that the large and negative Fermi contact term dominates this interaction." @default.
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- W2092161877 date "1988-11-01" @default.
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- W2092161877 title "15N-13C spin coupling as a probe of electronic structure in benzenediazonium ions: INDO—SOS—MO calculations and steric inhibition of resonance" @default.
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- W2092161877 doi "https://doi.org/10.1002/mrc.1260261104" @default.
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