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- W2092163962 abstract "Abstract Six new μ-oxamido heterobinuclear complexes have been synthesized and identified as [Cu(oxae)Fe(L)2]SO4, where oxae denotes the N,N′-bis(2-aminoethyl)oxamido dianion and L represents 1,10-phenanthroline(phen); 5-nitro-1,10-phenanthroline (NO2-phen); 5-chloro-1,10-phenanthroline (Cl-phen); 5-methyl-1,10-phenanthroline (CH3-phen); 2,2′-bipyridine (bpy) and 4,4′-dimethyl-2,2′-bipyridine (Me2bpy). Based on the elemental analyses, spectroscopic studies, magnetic moments at room temperature and molar conductivity measurements, extended oxamido-bridged structures consisting of a copper(II) and an iron(II) ions, which have a square planar environment and an octahedral environment, respectively, are proposed for these complexes. The [Cu(oxae)Fe(bpy)2]SO4 (1) and [Cu(oxae)Fe(phen)2]SO4 (2) complexes have been characterized by variable temperature magnetic susceptibility (4.2–300 K) and the observed data were least-squares squares fitted to the susceptibility equation derived from the spin Hamiltonian including single-ion zero-field interaction for the iron(II) ion, H = −2J S 1 · S −D S z1 2 , giving the exchange integrals J = −30.6 cm−1 for (1) and J = −31.8 cm−1 for (2). These results are commensurate with antiferromagnetic interactions between adjacent metal ions within each molecule." @default.
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- W2092163962 date "1998-01-01" @default.
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- W2092163962 title "Synthesis and magnetic studies of oxamido-bridged heterobinuclear copper(II)-iron(II) complexes" @default.
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- W2092163962 doi "https://doi.org/10.1016/s0277-5387(97)00334-3" @default.
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