Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092166639> ?p ?o ?g. }
- W2092166639 endingPage "230" @default.
- W2092166639 startingPage "221" @default.
- W2092166639 abstract "Abstract In this article, properties of laboratory and industrially prepared Mg–Al layered double hydroxides (LDH) with Mg:Al molar ratios varied in the range from 2 to 4 were compared. Physico-chemical properties of the studied materials were investigated with XRD, SEM, N2 physisorption, TGA and CO2-TPD methods. Catalytic behavior of the LDH samples was examined in the liquid phase aldol condensation of furfural and acetone at 20 and 60 °C. It was found that LDH from the small-scale preparation have different physico-chemical characteristics than the LDH materials originating from the large-scale (industrial) preparation which is also reflected in their catalytic behavior. As-synthesized laboratory LDH catalysts are phase-pure crystalline samples with hydrotalcite structure while the industrial materials also possess MgO as admixture. The laboratory samples possess larger BET surface area and mesopore volume in comparison with the industrially prepared ones. Despite the similarity in basic properties of the studied materials, the samples with molar ratio Mg:Al = 3 in both groups of LDH using different method of preparation possess the best activity in aldol condensation. Generally, the calcined laboratory samples are more active than the industrial materials in the reaction. This is explained by the better textural properties of the former ones and their susceptibility to in-situ reconstruction in the presence of water formed during the reaction." @default.
- W2092166639 created "2016-06-24" @default.
- W2092166639 creator A5002847082 @default.
- W2092166639 creator A5004215459 @default.
- W2092166639 creator A5035145366 @default.
- W2092166639 creator A5041930090 @default.
- W2092166639 creator A5044986040 @default.
- W2092166639 date "2015-03-01" @default.
- W2092166639 modified "2023-09-24" @default.
- W2092166639 title "Comparative study of physico-chemical properties of laboratory and industrially prepared layered double hydroxides and their behavior in aldol condensation of furfural and acetone" @default.
- W2092166639 cites W12567091 @default.
- W2092166639 cites W1964876885 @default.
- W2092166639 cites W1971443013 @default.
- W2092166639 cites W1975111239 @default.
- W2092166639 cites W1977371274 @default.
- W2092166639 cites W1982070339 @default.
- W2092166639 cites W1984209585 @default.
- W2092166639 cites W1985302254 @default.
- W2092166639 cites W1989713671 @default.
- W2092166639 cites W1990264245 @default.
- W2092166639 cites W1991542270 @default.
- W2092166639 cites W1998321859 @default.
- W2092166639 cites W2002781626 @default.
- W2092166639 cites W2004133865 @default.
- W2092166639 cites W2015772487 @default.
- W2092166639 cites W2018332356 @default.
- W2092166639 cites W2022755037 @default.
- W2092166639 cites W2024659723 @default.
- W2092166639 cites W2033624772 @default.
- W2092166639 cites W2042544277 @default.
- W2092166639 cites W2051581790 @default.
- W2092166639 cites W2059153933 @default.
- W2092166639 cites W2059602920 @default.
- W2092166639 cites W2059874205 @default.
- W2092166639 cites W2067619206 @default.
- W2092166639 cites W2087548647 @default.
- W2092166639 cites W2094975043 @default.
- W2092166639 cites W2096387219 @default.
- W2092166639 cites W2112027085 @default.
- W2092166639 cites W2148613179 @default.
- W2092166639 cites W2152630635 @default.
- W2092166639 doi "https://doi.org/10.1016/j.cattod.2014.03.010" @default.
- W2092166639 hasPublicationYear "2015" @default.
- W2092166639 type Work @default.
- W2092166639 sameAs 2092166639 @default.
- W2092166639 citedByCount "52" @default.
- W2092166639 countsByYear W20921666392016 @default.
- W2092166639 countsByYear W20921666392017 @default.
- W2092166639 countsByYear W20921666392018 @default.
- W2092166639 countsByYear W20921666392019 @default.
- W2092166639 countsByYear W20921666392020 @default.
- W2092166639 countsByYear W20921666392021 @default.
- W2092166639 countsByYear W20921666392022 @default.
- W2092166639 countsByYear W20921666392023 @default.
- W2092166639 crossrefType "journal-article" @default.
- W2092166639 hasAuthorship W2092166639A5002847082 @default.
- W2092166639 hasAuthorship W2092166639A5004215459 @default.
- W2092166639 hasAuthorship W2092166639A5035145366 @default.
- W2092166639 hasAuthorship W2092166639A5041930090 @default.
- W2092166639 hasAuthorship W2092166639A5044986040 @default.
- W2092166639 hasConcept C121332964 @default.
- W2092166639 hasConcept C161790260 @default.
- W2092166639 hasConcept C175583648 @default.
- W2092166639 hasConcept C178790620 @default.
- W2092166639 hasConcept C185592680 @default.
- W2092166639 hasConcept C18616679 @default.
- W2092166639 hasConcept C200093464 @default.
- W2092166639 hasConcept C2779719330 @default.
- W2092166639 hasConcept C2781213060 @default.
- W2092166639 hasConcept C61156836 @default.
- W2092166639 hasConcept C97355855 @default.
- W2092166639 hasConceptScore W2092166639C121332964 @default.
- W2092166639 hasConceptScore W2092166639C161790260 @default.
- W2092166639 hasConceptScore W2092166639C175583648 @default.
- W2092166639 hasConceptScore W2092166639C178790620 @default.
- W2092166639 hasConceptScore W2092166639C185592680 @default.
- W2092166639 hasConceptScore W2092166639C18616679 @default.
- W2092166639 hasConceptScore W2092166639C200093464 @default.
- W2092166639 hasConceptScore W2092166639C2779719330 @default.
- W2092166639 hasConceptScore W2092166639C2781213060 @default.
- W2092166639 hasConceptScore W2092166639C61156836 @default.
- W2092166639 hasConceptScore W2092166639C97355855 @default.
- W2092166639 hasFunder F4320321006 @default.
- W2092166639 hasFunder F4320322741 @default.
- W2092166639 hasLocation W20921666391 @default.
- W2092166639 hasOpenAccess W2092166639 @default.
- W2092166639 hasPrimaryLocation W20921666391 @default.
- W2092166639 hasRelatedWork W1988060478 @default.
- W2092166639 hasRelatedWork W1998904072 @default.
- W2092166639 hasRelatedWork W2013489139 @default.
- W2092166639 hasRelatedWork W2067516851 @default.
- W2092166639 hasRelatedWork W2170430502 @default.
- W2092166639 hasRelatedWork W2275734348 @default.
- W2092166639 hasRelatedWork W2886042258 @default.
- W2092166639 hasRelatedWork W2947258708 @default.
- W2092166639 hasRelatedWork W3084210383 @default.
- W2092166639 hasRelatedWork W4306154502 @default.
- W2092166639 hasVolume "241" @default.