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- W2092182445 abstract "When electrical contact is broken between electrodes of iron and tin immersed in boiling 0.2M citric acid containing Sn(II), the potential of the iron moves in the noble direction for a short time and then in the active direction for a much longer time until a steady‐state value is reached within several hours. The largest shift in the noble direction and the slowest rate of return to a steady‐state value were obtained with pure iron. Potential measurements, electron microscope studies, electron diffraction studies, studies using radioactive tin, and measurements using elliptically polarized light were made in order to explain the phenomenon. The following hypothesis was proposed to explain the potential changes observed. When iron and tin are in electrical contact under the experimental conditions used, an iron‐tin alloy is formed on the iron surface. Simultaneously with the formation of the alloy, or as a secondary process, there is formed a small amount of excess tin. The shift to the noble value after uncoupling is a result of the dissolution of this excess tin. The slow drift to the steady‐state value is a consequence of the dissolution of a minute amount of the iron‐tin alloy with the resulting formation of a definite ratio of anodic/cathodic surface area." @default.
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- W2092182445 date "1964-01-01" @default.
- W2092182445 modified "2023-10-16" @default.
- W2092182445 title "A Hypothesis for the Change in Potential of Iron on Uncoupling from Tin in Citric Acid Solution" @default.
- W2092182445 doi "https://doi.org/10.1149/1.2426138" @default.
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