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- W2092186766 abstract "Abstract Vapor pressure vs. H2O content studies demonstrate that phosphorylcholine chloride calcium salt forms two hydrates, a monohydrate and a tetrahydrate, in the range 0–4 mol H20 mol−1 of salt; there is no dihydrate or trihydrate. Equilibrium vapor pressure measurements show that ΔH0 of dissociation per mol H20 lost is greater for the tetrahydrate (16.08 kcal mol−1) than for the monohydrate (12.49 kcal mo−1); the lower stability of the tetrahydrate arises from entropy effects. The IR spectrum of the tetrahydrate is that of a framework clathrate hydrate and suggests that the -P03 group may act as a very weak hydrogen-bond acceptor. In the monohydrate the -P03 group is not involved in hydrogen bonding. Neither hydrate contains POH bonds." @default.
- W2092186766 created "2016-06-24" @default.
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- W2092186766 date "1991-09-01" @default.
- W2092186766 modified "2023-09-25" @default.
- W2092186766 title "Hydrogen bonding Part 38. IR and thermodynamic study of phosphorylcholine chloride calcium salt tetrahydrate and monohydrate" @default.
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- W2092186766 doi "https://doi.org/10.1016/0022-2860(91)85065-b" @default.
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